S1E142: Miare City! New Encounters

Liko and the others have arrived in Miare City,and go visit the Handsome House, where they meet Matiere and her assistant Navi. Navi really loves Pokémon,and takes a great interest in Liko and the others. Just then, Matiere receives a request to locate a Melecie. And when the group starts investigating, they learn that a large blonde man wearing a dougi was accompanying it.